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Amarisolide monohydrate, a 2-(β-glucosyl)neoclerodane

Organismo relacionado

Autor(es):

Toscano Rubén A.
Maldonado Emma
Ortega Alfredo
Cárdenas Jorge

Revista: Acta Crystallographica Section C: Crystal Structure Communications

Año: 2001

Volumen: C57

Issue: 7

Páginas: 846-847

Página Inicial (en serio?): 846

Capítulo del libro: NULL

Editores del libro: NULL

Nombre del libro: NULL

Editorial: NULL

Lugar: NULL

Abstract:

The absolute configuration of the neoclerodane glycoside amarisolide, presented here as the monohydrate, C26H36O9·H2O, has been determined by association with the known configuration of the glucose moiety. Its structure was established as 2[β]-(O-[β]-D-gluco­pyran­osyl)­neocleroda-3,13(16),14-trien-15,16-epoxy-18,19-olide. Extensive hydrogen bonding among the hydroxyl groups of the sugar moiety forms layers which are interconnected by water molecules.

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